Dr. Mónica H. Pérez-Temprano

Catalysis

Group Leader:

Mónica H. Pérez –Temprano

Administrative Support: 

Núria Planella

Postdoctoral Researchers:

Sara Martínez de Salinas (until Feb.)

PhD Students:

Sara López Resano / Jesús San José (until Feb.) / Angel Luís Mudarra (until Feb.) / Jiayu Zhang

Master Students:

Clara Velasco Martínez (until July) / Sergio Barranco

Summary

The group of Dr. Pérez-Temprano is focused on the development of new synthetic catalytic methods with cobalt through detailed knowledge of the catalytic process. To develop their research projects, they apply different approaches, from synthetic organic chemistry to mechanical studies, including the capture of highly reactive reaction intermediates.

Publications

Weakly Coordinated Cobaltacycles: Trapping Catalytically Competent Intermediates in Cp*CoIII Catalysis
Martínez de Salinas, S.; Sanjosé-Orduna, J.; Odena, C.; Barranco, S.; Benet-Buchholz, J.; Perez-Temprano, M. H.
Angew. Chem. Int. Ed. 2020, 59 (15), 6239-6243

Intramolecular C(sp3)–H Bond Amination Strategies for the Synthesis of Saturated N-containing Heterocycles
Zhang, J.; Pérez-Temprano, M. H.
Chimia 2020, 74 (11), 895-903

Emerging unconventional organic solvents for C–H bond and related functionalization reactions
Yu, C.; Sanjosé-Orduna, J.; Patureau, F. W.; Pérez-Temprano, M.H.
Chem. Soc. Rev. 2020, 49, 1643-1652

Weakly Coordinated Cobaltacycles: Trapping Catalytically Competent Intermediates in Cp*CoIII Catalysis
Martínez de Salinas, S.; Sanjosé-Orduna, J.; Odena, C.; Barranco, S.; Benet-Buchholz, J.; Perez-Temprano, M. H.
Angew. Chem. Int. Ed. 2020, 59 (15), 6239-6243

 

Projects

COBIST
Alternatives to Traditional Cross-Coupling Reactions to promote C-C Bond Formation: Investigation of Bimetallic Systems and Cobalt Catalysis
Ministerio | Ref: CTQ2016-79942-P

CHAOS
C-H Activation in Organic Synthesis
COST-European Cooperation in Science and Technology | Ref: EU Cost Action 15106

SMACT
Small molecules activation: From climate change responsible to sustainable and renewable feedstock
Ministerio | Ref: EUIN2017-87980

ICIQ-Starting Career Programme
Ministerio, Severo Ochoa | Ref: ICIQ-SCP

 

Theses supervised

Angel Mudarra
February 14th, 2020
Universitat Rovira i Virgili
«Coinage Metal Complexes in C-C and C-N Bond-Forming Reactions»

Jesús San José
February 21st, 2020
Universitat Rovira i Virgili
«Trapping Elusive Cp*CoIII Metallacycles: Implications in C–H Functionalization Processes»

 

Features

Kleij and Pérez-Temprano recognised by the RSEQ
https://www.iciq.org/kleij-and-perez-temprano-recognised-by-the-rseq/